Additional scavenging is done with a merge collector and/or an X-pipe - plus a correct length of pipe of the correct diameter after it. No need for further scavenging.
The best work is done by headers scavenging the cylinders, unless the rest of the exhaust is built too small and/or restrictive in other means, (mufflers), and keeping the headers from being their most efficient, no more should be needed or would do any good.
For smallblock powered street vehicles I use 3" collectors into either ; a 3" H-pipe setup and long tapered 3" to 2 1/2" reducers, or the reducers first and 2 1/2" H-pipe setup. Then into 2 1/2" mandrel-bent pipes all the way to the back or at least over the axle. The mufflers need to be as far back as practical, and with at least an approx. 14" pipe afterwards.
Exhaust gases cool as they travel,(and slow down), and therefore also take up less space within the pipe. Sooo ... tailpipes can actually be a size smaller with no ill effect !
Just look at any racing exhausts to see what works within that engines operating range, the brightest minds the world has to offer have had decades to reengineer them !